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HALOGENFREE

低煙無鹵電纜培訓WELCOMEatGLTSEMINAR 2002-02-20RhodeIslandClub,USA

2001-01-01Volendam,NL

2000-11-11Kitzsteinhorn,A

1996-04-11DusseldorfAirport,DHarmonizedHalogenFreeCables

協調標準下的低煙無鹵電線InternationalDesignationH05Z1Z1-FHD21.14國際統一名稱H05Z1Z1-FHD21.14(flexiblecablesinsulatedandsheathedwithhalogen-freethermoplasticcompounds)低煙無鹵熱塑絕緣和護套的軟線InternationalDesignationH05(7)Z1-U,R,KHD21.15國際統一名稱H05(7)Z1-U,R,KHD21.15(singlecorecablesinsulatedwithhalogenfreethermoplasticcompoundforfixedwiring)低煙無鹵熱塑絕緣單芯固定線InternationalDesignationH07Z-U,R,KHD22.9國際統一名稱H07Z-U,R,KHD22.9(singlecorenon-sheathedcablesforfixedwiringhavingcross-linkedpolymerandhavinglowemissionofsmokeandcorrosivegases)含有交聯聚合物和低煙以及腐蝕性氣體的單芯無護套固定線InternationalDesignationH07ZZ-FHD22.13國際統一名稱H07ZZ-FHD22.13(flexiblecablesinsulatedandsheathedwithcross-linkedpolymerandhavinglowemissionofsmokeandcorrosivegases)護套和絕緣為交聯聚合物并含有低煙和腐蝕性氣體的軟線MainTestStandardsforHF

低煙無鹵電線的主要測試標準

Non-HalogenVerification無鹵驗證

DINVDE0472part815,EN50267-2-1, DINVDE482part267,IEC60754-1

Determinationoftheamountofhalogenacidgas;theproofofhalogeniseffectedbychemicalanalysis. ThustheproofofhalogenacidcontentlikeHCLandHBristheresult.Theaccuracyofthistestisupto5mg/g,notformaterialscontaininglessthanthat.

判定鹵酸氣含量,鹵素的驗證受化學分析影響。測出鹵酸氣所含物質如:氯化氫和溴化氫為該驗證結果。本測試精度所要求材料含量高達5mg/g,若材料含量少于此要求則不適用。Standards

標準

DINVDE0472part815 Non-HalogenVerificationtestingofCables,WiresandFlexibleCords

適用于電纜、電線和軟線的無鹵驗證測試TestMethodA:totestforhalogensChlorine,Bromine,Iodine測試法A:測試鹵素:氯、溴、碘

TestMethodB:totestforthehalogenFluorine測試法B:測試鹵素:氟TestGoalsinEN/HDStandards

EN和協調標準的測試目標

0 HD21.14Halogen:FluroineChlorine

Ifnegative:stoptest

andBromineIfpositive:continue

鹵素:氟、氯和溴若結果為“-”:停止測試若結果為“+”:繼續1EN50267-2-2 pHvalueand ≥4,3 Conductivity ≤10μS/mmpH值和導電率2EN50267-2-1 ContentofHCL

≤0,5%

氯化氫含量

3 EN60684-2

Fluorinecontent

≤0,1%

氟含量

acceptmaterialTestStandards

測試標準

CorrosivityofCombustionGases燃燒氣體的腐蝕性

DINVDE0482part2672-2,EN50267-2-2, IEC60754-2andHD602

Insulationandjacketmaterialsaretobeputinthemoveablefurnace,pre-heatedto750to800°C.Theburninggasisconductedthroughtwogas-washingbottles.Thetestshallberegardedaspassedwhenthemeasuredconductivityis≤10μS/mm.Duringthistestallthenotdesiredcomponentsofthematerialsareprecipitatedsuchasallhalogens,sulphurandnitrogen.Thecorrosiontestofgasescausedbyfireiscarriedouttothetestmaterials,notthecompletecablesamples

將絕緣和護套材料放入移動烤箱中預熱至750℃到800℃。將燃燒氣體導至兩個洗氣瓶。當測到導電率≤10μS/mm時測試認為通過。測試過程中,材料中所有無要求的元素會沉淀,如所有鹵素,硫和氮。由燃燒產生的腐蝕性氣體的測試只針對測試材料而非整個電線樣品。TubeFurnace–Drawing

烤箱管道圖MeasuringofCorrosivity

腐蝕性測量TubeFurnaceThepresenceofHalogencomponentswillbedetectedinsmallestquantitiesThesampleofinsulationorjacketmaterialisinthesilicatube,onacombustionboat出現的鹵素成分將取最小量測量絕緣或護套材料樣品放入二氧化硅試管中,置于燃燒皿上AirEntryandTubeforFurnace

syntheticair,speedrate1l/minFurnacewithEntryandExitTubeFurnaceWashingBottleGasWashingBottlesResultofTestHalogensandTestStandards

鹵素和測試標準

HalogencontentofHCLundHBrofinsulation:

絕緣材料中鹵素:氯化氫和溴化氫的含量EN50267-2-1(VDE482Teil267-2-1):max0,5% FluorineHFofinsulation:絕緣材料中:氟化氫

EN60684-2(VDE0341Teil2):max0,1% HCLandHBrofsheath:護套材料中:氯化氫和溴化氫

EN50267-2-1(VDE482Teil267-2-1):max0,5% FluorineHFofsheath:

護套材料中:氟化氫EN60684-2(VDE0341Teil2):max0,1%

LSF LSHF/LSZH

Therearemanytermsusedtodescribeacable‘sbehaviorduringafire.Mostdealwiththelevelofsmokeandpoisonousfumesgivenoff.LSFcables(LowSmoke&Fume)aresometimesnomorethanmodifiedPVCgivingoffanythingupto18%HClemissions!Cablesthatgiveoffbelow0.5%ofHClareclassedasLowSmokeHalogenFree(LSHF),LowSmokeZeroHalogen(LSZH)etc.

描述電線在燃燒過程中狀態的術語很多。大部分都與釋放出的煙霧指數和有毒氣體相關。電線釋放出低于0.5%的氯化氫稱為低煙無鹵電線,或低煙零鹵線等。H05Z1Z1-FH05Z1Z1-Fisalightduty,harmonized,flexible,halogen-free,blackjacketedmulticonductor300/500V.Europeancord.Recommendedwhenhalogen-free,low-smokeandcorrosivegaspropertiesarerequiredincaseoffire.Applicationsincludeconnecting

electricalappliancesundermediummechanicalstressesenvironmentsinoffices,kitchensandhouseholds.H05Z1Z1-Fcancommonlybefoundinconnectionstorefrigerators,washingmachinesandspin-dryers.Thesecablescanalsobeusedincookingandheatingapparatusifnotindirectcontactwithhotpartsoftheapparatus.H05Z1Z1-F為輕型、符合協調標準、細軟、無鹵、黑色護套多芯線300/500V歐洲線型。為了防火,推薦使用符合無鹵、低煙和腐蝕性氣體要求的電線。此類電線適用于連接辦公室、廚房和家庭中受介質機械應力環境的電器。H05Z1Z1-F通常用于冰箱,洗衣機和自旋式干燥機。若不直接與器具的熱部件連接,此類電線還可用于烹飪和加熱器具。H07ZZ-FH07ZZ-Fisaharmonized,heavy-duty,flexible,halogen-free,blackjacketedmulti-conductor450/750V.Europeancable.Recommendedforuseinelectricalequipmentundermediumstressindoors;notsuitableforcontinuousoutdooruse.Recommendedwhenhalogen-freelowsmokeandcorrosivegaspropertiesarerequiredincaseoffire.H07ZZ-Fcablesareusedforequipmentinindustryworkssuchasboilers,heatingplates,handlamps,electrictoolssuchasdrills,circularsaws,inhomeworktoolsandtransportablemotorsormachinesatsite.H07ZZ-F為符合協調標準、重型、細軟、無鹵、黑色護套多芯線450/750V歐洲線纜。推薦用于室內電器設備;不適合戶外長期使用。為了防火,推薦使用符合無鹵、低煙和腐蝕性氣體要求的電線。H07ZZ-F型線纜用于工業用途的設備,如:鍋爐,加熱板,手提燈,電動工具如:電鉆,圓盤鋸,家用工具和工地用運輸馬達或機械。S03Z1Z1H2-F

S03Z1Z1-FThermoplasticCable熱塑電線HD21.14S1:2003Acc.toVDE-RegNr7907(S03Z1Z1)and7908(S05Z1Z1)Temperatureatloadacc.toHD+70°C按協調標準帶負荷溫度+70°CTemperaturerange(3000h)–20°Cto

+80°CInsulation絕緣HalogenfreePolymercompoundTI6Acc.toHD21.14根據HD21.14無鹵聚合材料:TI6Sheath護套HalogenfreePolymercompoundFRNC=FlameRetardantNonCorrosiveTM7

無鹵聚合物:FRNC=阻燃非腐蝕性TM7Acc.toHD21.14Voltage300/300VU0/UInsulationandSheath

Materials

絕緣和護套材料ThermoplastsandTPE熱塑性材料和TPEPVC,PE,PA,PP–TPE-U,TPE-E,TPE-O,TP-CElastomers合成橡膠CR,CSM,CM,EPR,EVA,SIRThermoplastics/Elastomers

Crosslinked

by

Irradiatian熱塑/合成橡膠交聯輻射XLPE,XTPU,mod.X-PER,XPVDF,XETFEHighTemperature

Materials高溫材料X-PER,PEIC,PVDF,ETFE,SIR,FEP,PI,PEEK,PFA,PTFEHalogenfree,FlameRedardant

Compounds無鹵,阻燃聚合物PE-Cop,XPE-Cop,TPE-U,TPE-U,TPE,PP,EVA,TP-CHalogenFreeFlameRetardant

無鹵阻燃Halogen-free:Polymerslikepolyethylene(PE)orpolypropylene(PP)arehalogen-free.Thesematerialsareeasyflammableandnotself-extinguishing.無鹵:聚合物如PE或PP都為無鹵。這些材料都易燃且不會自動熄滅Halogen-freecablesforsecurityrequirementsmustbehardlyflammableandself-extinguishing.Thishappensbyusingthespecialpolymercompounds,containingtheconsiderablepercentageofflameprotectivematerials.符合安全要求的無鹵線纜必需不易燃且能自動熄滅。這樣就需要用特殊的聚合物,該材料含有相當比例的防火材料。Suchkindofprotectivematerialsconsistof,forexample,analuminumhydroxidewhichononesidecoolsthefirelocationbysettingfreecrystalwaterandontheothersidethereleasedwatervaporhinderstheadmittanceofoxygenandtherebythissuffocatestheflame.此類防火材料包含,如:氫氧化鋁,一方面通過結成水晶液降低火焰溫度,另一方面釋放水蒸氣阻止氧氣進入而滅火。ReasonforHalogenFree

ToxicGasescankillorharmhumanbeings有毒氣體對人體有害甚至致命Damagetoexpensiveequipmentthroughcorrosion

腐蝕昂貴設備

- Halogen-freecableswillnotcausecorrosiontometals.

無鹵電線不會腐蝕金屬 - Whenhalogen-containingcablesburn,thegasesgenerated incombustionofthesheathingandinsulationmaycause corrosion.

當含有鹵素的線纜燃燒時,絕緣和護套燃燒產生的氣體會導致腐蝕 - Thesecondaryeffectsafterafireareoftenmanytimeslarger thanthedamagescausedbythefireitself.

火災造成的的第二影響往往比火災本身造成的危害更大BurningBehavior–Self-Extinguishing

燃燒特性-自動熄滅 DINVDE0482-332-1

IEC332-1

Sample

1

樣品

Length

60cm

長度

Duration

<65sec

時間

IEC332-1/EN60332-1

old:EN50265-2-1TestonsingleverticalcableTestmethodB在單根垂直電線上測試測試法BVerticalflametestIEC332-3

垂直火焰測試

Burningbehavioronbunchedcables束狀電纜的燃燒特性EN50266-2-4flamepropagation,

火焰延伸 TestmethodC測試法CSmokeDensityChamber

煙霧密度箱ChamberThechamberis3x3x3mandhasaphotometricsystemwithalightsourceof100W容器為3X3X3m,且帶有光源為100W的光度測定系統Abathwithalcohol,abovethebathinhorizontaldirectionthecablesamples:alcoholisignited帶酒精的容器,電線樣品置于容器上方水平線方向:酒精點燃Thephotocellregisterstheweakeningoflight光電管記錄光的弱化Afterextinguishingofalcoholthelightshouldstayover5minandnotgetweakerortestdurationof40min酒精燃燒熄滅后光應保持超過5分鐘不變弱或測試持續40分鐘ComparisonbetweenPVCandHF

無鹵電線和PVC電線的比較SecurityCablesRHEYHALON?

Security

Cables

SecurityCables

Security

cables

are

products

thatwillnot

letofftoxicandcorrosive

gasesincaseoffire. Some

cables

haveafire

integrity

that

gurantees

the

function

of

importantsystemsfor

evacuationandfire fighting. The

cables

are

usedinbuildings

with

hug

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