2﹣++2學(xué)年山東省濟南高三（上）末化學(xué)試2﹣++2一選題本共小題每題2分共20分每題有個項符題要。ABCDABCXDXYWXXYZXYAYXWBWZYCYDXYNaCsANaClCsClBNaClCsClCNaClCsClClDNa

A

24322432B

CC

D

ABCD1molHABCDCH

﹣﹣﹣3224﹣﹣﹣322442443ABCDHCOOHAHCOOH+3OH2eHCOBAHSOCDpHBaSOASrCOKBCD二選題本共題每題，20。小有個兩選符題要求全選得，

4243358選但全得2分，有錯424335811

A

，B度MgAlAlCAgClNaClAgIK

AgNONaID

液溶AABBCDDAHNOBC

22+3+222﹣+2﹣1﹣123D22+3+222﹣+2﹣1﹣123OOHFe+HO+HFeO+OHAABNHOOH+HCOHNDMOHCHHAB1CD2540mL0.1molLH0.1molLNaOH

+2﹣23+﹣323h12232323Bp+2﹣23+﹣323h12232323Bp2p2AXcHSOHSOOHBYNaHSOCK10DZXYW

4.14三解題共5小題，分分1g+COgOHgvkxCOHk正正逆逆

xOHvvkkx正逆正逆HOH①eq\o\ac(△,H)

K

K

kk正逆②K

③CO1121

232221222233343362H2322212222333433622SRMCHOHggeq\o\ac(△,H)eq\o\ac(△,)H+HOgeq\o\ac(△,H)eq\o\ac(△,)0CHOHCO2CHOHABCHOHCDICDIrl14350KIrBrIr62ICDIrl

1mol

3IrO2

﹣32A2﹣1212121223﹣32A2﹣1212121223

xyzIrO

Ir

OIrOIrOapmcpmcmIrO

g732HClZnCl[ZnCl]1a2K5503750KKKK4LiCoOFe

﹣81524224xy﹣81524224xyn2322324622223①②③K6.310KOH]123CoC45NaFeSOOH4.850g100.00mL25.00mLKI0.2500molL

1

NaSI+2NaSO30.00mL25.00mL1.165gSMacMillan

22292229XOCHR+HClRNH+

+HClRRRX1BCE2CG3F*4

H5

36353+﹣3432++++學(xué)年山東省36353+﹣3432++++試題解析一選題本共小題每題2分共20分每題有個項符題要。AABHClCDDABCXDDAXYNAlN2pABYZNAlO

O

AlCYZNNONDXYWCXYZAAABC16CDCsNaA.AC.NaClC

327328﹣﹣3﹣﹣﹣3+++﹣222426++﹣22433824327328﹣﹣3﹣﹣﹣3+++﹣222426++﹣2243382424543DAABBCD132mol3molAABCCDDAOHspABC

CHOHsp

BCCDNsp6DHCOOH2e+3OHHCOOAB通+4eHKAHSOC通DO+4e+6H2HOpHDA.HCOSrCONHSOSrCOKAB.NH

22435852252﹣+4++3+﹣222272+﹣42﹣﹣323++222435852252﹣+4++3+﹣222272+﹣42﹣﹣323++2++﹣83432D二選題本共題每題，20。小有個兩選符題要求全選得，選但全得2分，有錯得0分。11A.23AMgSOAlSOBC.AgNODAAHOABCNHNHDBCAOBNHeOH+HCOHCDM+2eHFeFe+H+HFe+HOHNHOMOHNOH1DAB12CDDAXSO+cHSO+cOHNa+cHSO+cHSOcNaHSO+cH

2﹣32+3﹣﹣﹣8333+++﹣﹣82﹣373+27h1﹣6.8122﹣﹣﹣﹣3336362﹣32+3﹣﹣﹣8333+++﹣﹣82﹣373+27h1﹣6.8122﹣﹣﹣﹣3336363633BC362233252p26B3.19OHcH2c+cHSO+cOH+cHNaHSOBCH

cHK

10DHSOHSOHSOSOHSOHSOYXW三解題共5小題，分分OHCK

kk正逆kkk正逆正逆②pHCOH2molxmol2mol4xmolCO1mol3mol2xmol+1molxmol+xmol3mol2xmolOH100%H7.5molCOOH0.75molH

3

OH

K③CO1422

7463725232A2A2252272221CO7463725232A2A225227222142

Ir75d44d2IrNN

N4C1molN4mol432+624OIr位體與O的Ir

則MaN10

30

g/mol

aN2AZnOHCl+HCl+HO

+HO3IIAKKBAZnClNBKK4HClB

+2424+2+27++2+22234﹣2+723232464232223﹣2﹣1﹣32﹣+2424+2+27++2+22234﹣2+723232464232223﹣2﹣1﹣32﹣4﹣324﹣3++﹣﹣++﹣+423466422262222232LiCoO2LiCoO2LiO2LiCoO8Li3CoCO45

+5I

+II+2NaSOSISn4nInNaSOLLmL2.5010BaCl

mol7.50mol

6.03﹣

5.00

0.02NaOH4.850g0.03mol6.02molnNaOH0.03mol3+nNa0.02mol2+nOH2Na0.01﹣

molxymnnNa

OH

﹣

7.010.030.028.0646NaFeOHNaFeSOOHBCHCHCHClCClCHCHOHClBHClOC