1、物理化學習題集匯編 第一部分概念及術語ABCDEFGHIJKLM NOPQRSTUVWX Y Z第二部分練習題 第三部分模擬題及答案 TOC o 1-5 h z 前言15 HYPERLINK l bookmark2 o Current Document 概念及術語16 HYPERLINK l bookmark4 o Current Document BET 公式 BET formula16 HYPERLINK l bookmark6 o Current Document DLVO 理論 DLVO theory 16 HYPERLINK l bookmark8 o Current Documen

2、t HLB 法 hydrophile-lipophile balance method 16 HYPERLINK l bookmark10 o Current Document pVT 性質 pVT property16 HYPERLINK l bookmark12 o Current Document Z 電勢 zeta potential16 HYPERLINK l bookmark14 o Current Document 阿伏加德羅常數Avogadro number.16 HYPERLINK l bookmark16 o Current Document 阿伏加德羅定律Avogadro

3、 law16 HYPERLINK l bookmark18 o Current Document 阿累尼烏斯電離理論 Arrhenius ionization theory 16 HYPERLINK l bookmark20 o Current Document 阿累尼烏斯方程Arrhenius equation17 HYPERLINK l bookmark22 o Current Document 阿累尼烏斯活化能 Arrhenius activation energy17 HYPERLINK l bookmark24 o Current Document 阿馬格定律 Amagat law1

4、7 HYPERLINK l bookmark26 o Current Document 艾林方程 Erying equation17 HYPERLINK l bookmark28 o Current Document 愛因斯坦光化當量定律Einstein s law of photochemical equivalence17 HYPERLINK l bookmark30 o Current Document 愛因斯坦一斯托克斯方程Einstein-Stokes equation17 HYPERLINK l bookmark32 o Current Document 安托萬常數Antoine

5、constant17 HYPERLINK l bookmark34 o Current Document 安托萬方程Antoine equation17 HYPERLINK l bookmark36 o Current Document 盎薩格電導理論 Onsagers theoryof conductance17 HYPERLINK l bookmark38 o Current Document 半電池 half cell17 HYPERLINK l bookmark40 o Current Document 半衰期 half time period18 HYPERLINK l bookma

6、rk42 o Current Document 飽和液體 saturated liquids18 HYPERLINK l bookmark44 o Current Document 飽和蒸氣 saturated vapor18 HYPERLINK l bookmark46 o Current Document 飽和吸附量saturated extent of adsorption18 HYPERLINK l bookmark48 o Current Document 飽和蒸氣壓 saturated vaporpressure18 HYPERLINK l bookmark50 o Current

7、 Document 爆炸界限explosion limits18 HYPERLINK l bookmark52 o Current Document 比表面功specific surface work18 HYPERLINK l bookmark54 o Current Document 比表面吉布斯函數 specific surface Gibbs function18 HYPERLINK l bookmark56 o Current Document 比濃粘度reduced viscosity18 HYPERLINK l bookmark58 o Current Document 標準電動

8、勢 standard electromotive force18 HYPERLINK l bookmark60 o Current Document 標準電極電勢 standard electrode potential18 HYPERLINK l bookmark62 o Current Document 標準摩爾反應焓 standard molar reaction enthalpy18 HYPERLINK l bookmark64 o Current Document 標準摩爾反應吉布斯函數standard Gibbs function of molar reaction18 HYPER

9、LINK l bookmark66 o Current Document 標準摩爾反應熵standard molar reaction entropy19 HYPERLINK l bookmark68 o Current Document 標準摩爾焓函數standard molar enthalpy function 19 HYPERLINK l bookmark70 o Current Document 標準摩爾吉布斯自由能函數standard molar Gibbs free energy function19 HYPERLINK l bookmark72 o Current Docume

10、nt 標準摩爾燃燒焓standard molar combustion enthalpy19 HYPERLINK l bookmark74 o Current Document 標準摩爾熵 standard molar entropy19 HYPERLINK l bookmark76 o Current Document 標準摩爾生成焓 standard molar formation enthalpy19 HYPERLINK l bookmark78 o Current Document 標準摩爾生成吉布斯函數standard molar formation Gibbs function 1

11、9 HYPERLINK l bookmark80 o Current Document 標準平衡常數 standard equilibrium constant19 HYPERLINK l bookmark82 o Current Document 標準氫電極 standard hydrogen electrode19 HYPERLINK l bookmark84 o Current Document 標準態 standard state19標準熵 standard entropy20標準壓力 standard pressure20標準狀況 standard condition20表觀活化能

12、apparent activation energy20表觀摩爾質量 apparent molecular weight20表觀遷移數 apparent transference number20表面 surfaces20表面過程控制 surface process control20 HYPERLINK l bookmark86 o Current Document 表面活性劑 surfactants21 HYPERLINK l bookmark88 o Current Document 表面吸附量 surface excess21 HYPERLINK l bookmark90 o Curr

13、ent Document 表面張力surface tension21 HYPERLINK l bookmark92 o Current Document 表面質量作用定律surface mass action law21 HYPERLINK l bookmark96 o Current Document 波義爾定律 Boyle law21 HYPERLINK l bookmark98 o Current Document 波義爾溫度 Boyle temperature21 HYPERLINK l bookmark100 o Current Document 波義爾點 Boyle point21

14、 HYPERLINK l bookmark102 o Current Document 玻爾茲曼常數 Boltzmann constant22 HYPERLINK l bookmark104 o Current Document 玻爾茲曼分布 Boltzmann distribution 22 HYPERLINK l bookmark106 o Current Document 玻爾茲曼公式 Boltzmann formula22 HYPERLINK l bookmark108 o Current Document 玻爾茲曼熵定理 Boltzmann entropy theorem 22 HY

15、PERLINK l bookmark112 o Current Document 泊 Poise22 HYPERLINK l bookmark114 o Current Document 不可逆過程 irreversible process22 HYPERLINK l bookmark116 o Current Document 不可逆過程熱力學 thermodynamics of irreversible processes22 HYPERLINK l bookmark118 o Current Document 不可逆相變化irreversible phase change22 HYPER

16、LINK l bookmark120 o Current Document 布朗運動 brownian movement22 HYPERLINK l bookmark122 o Current Document 查理定律 Charle s law22 HYPERLINK l bookmark124 o Current Document 產率 yield23 HYPERLINK l bookmark126 o Current Document 敞開系統open system23 HYPERLINK l bookmark128 o Current Document 超電勢 over potenti

17、al23 HYPERLINK l bookmark130 o Current Document 沉降 sedimentation23 HYPERLINK l bookmark132 o Current Document 沉降電勢 sedimentation potential23 HYPERLINK l bookmark134 o Current Document 沉降平衡 sedimentation equilibrium23 HYPERLINK l bookmark136 o Current Document 觸變 thixotropy23 HYPERLINK l bookmark138

18、o Current Document 粗分散系統 thick disperse system23 HYPERLINK l bookmark140 o Current Document 催化劑 catalyst23 HYPERLINK l bookmark142 o Current Document 單分子層吸附理論mono molecule layer adsorption23 HYPERLINK l bookmark144 o Current Document 單分子反應 unimolecular reaction23 HYPERLINK l bookmark146 o Current Do

19、cument 單鏈反應 straight chain reactions24 HYPERLINK l bookmark148 o Current Document 彈式量熱計 bomb calorimeter24 HYPERLINK l bookmark150 o Current Document 道爾頓定律 Dalton law24 HYPERLINK l bookmark152 o Current Document 道爾頓分壓定律Dalton partial pressure law24 HYPERLINK l bookmark154 o Current Document 德拜和法爾肯哈根

20、效應Debye and Falkenhagen effect24 HYPERLINK l bookmark156 o Current Document 德拜立方公式Debye cubic formula24 HYPERLINK l bookmark158 o Current Document 德拜一休克爾極限公式Debye-Huckel s limiting equation24 HYPERLINK l bookmark160 o Current Document 等焓過程isenthalpic process24 HYPERLINK l bookmark162 o Current Docum

21、ent 等焓線 isenthalpic line24 HYPERLINK l bookmark164 o Current Document 等幾率定理theorem of equal probability24 HYPERLINK l bookmark166 o Current Document 等溫等容位Helmholtz free energy25 HYPERLINK l bookmark168 o Current Document 等溫等壓位Gibbs free energy25 HYPERLINK l bookmark170 o Current Document 等溫方程equatio

22、n at constant temperature25 HYPERLINK l bookmark172 o Current Document 低共熔點eutectic point25 HYPERLINK l bookmark174 o Current Document 低共熔混合物 eutectic mixture25 HYPERLINK l bookmark176 o Current Document 低會溶點lower consolute point25 HYPERLINK l bookmark178 o Current Document 低熔冰鹽合晶 cryohydric26 HYPER

23、LINK l bookmark184 o Current Document 第二類永動機perpetual machine of the second kind26 HYPERLINK l bookmark186 o Current Document 第三定律熵Third-Law entropy26 HYPERLINK l bookmark188 o Current Document 第一類永動機perpetual machine of the first kind 26 HYPERLINK l bookmark190 o Current Document 締合化學吸附association

24、chemical adsorption26 HYPERLINK l bookmark192 o Current Document 電池常數 cell constant26 HYPERLINK l bookmark198 o Current Document 電池電動勢 electromotive force of cells 26 HYPERLINK l bookmark200 o Current Document 電池反應 cell reaction27 HYPERLINK l bookmark202 o Current Document 電導 conductance27 HYPERLINK

25、 l bookmark204 o Current Document 電導率 conductivity27 HYPERLINK l bookmark206 o Current Document 電動勢的溫度系數temperature coefficient of electromotive force 27 HYPERLINK l bookmark208 o Current Document 電動電勢 zeta potential27 HYPERLINK l bookmark210 o Current Document 電功 electric work27 HYPERLINK l bookmar

26、k212 o Current Document 電化學electrochemistry27 HYPERLINK l bookmark214 o Current Document 電化學極化 electrochemical polarization27 HYPERLINK l bookmark216 o Current Document 電極電勢electrode potential27 HYPERLINK l bookmark220 o Current Document 電極反應reactions on the electrode.27 HYPERLINK l bookmark222 o Cu

27、rrent Document 電極種類type of electrodes27 HYPERLINK l bookmark224 o Current Document 電解池electrolytic cell 28 HYPERLINK l bookmark226 o Current Document 電量計coulometer28 HYPERLINK l bookmark228 o Current Document 電流效率 current efficiency28 HYPERLINK l bookmark230 o Current Document 電遷移electro migration28

28、 HYPERLINK l bookmark232 o Current Document 電遷移率 electromobility28 HYPERLINK l bookmark234 o Current Document 電滲 electroosmosis.28 HYPERLINK l bookmark236 o Current Document 電滲析electrodialysis28 HYPERLINK l bookmark238 o Current Document 電泳 electrophoresis28 HYPERLINK l bookmark240 o Current Documen

29、t 丁達爾效應Dyndall effect28 HYPERLINK l bookmark242 o Current Document 定容摩爾熱容 molar heatcapacity under constant volume28 HYPERLINK l bookmark244 o Current Document 定容溫度計Constant voIume thermometer28 HYPERLINK l bookmark246 o Current Document 定壓摩爾熱容molar heat capacity under constant pressure28 HYPERLINK

30、l bookmark248 o Current Document 定壓溫度計constant pressure thermometer.29 HYPERLINK l bookmark250 o Current Document 定域子系統 localized particle system29 HYPERLINK l bookmark252 o Current Document 動力學方程 kinetic equations29 HYPERLINK l bookmark254 o Current Document 動力學控制 kinetics control29 HYPERLINK l boo

31、kmark256 o Current Document 獨立子系統 independent particle system29 HYPERLINK l bookmark258 o Current Document 對比摩爾體積 reduced mole volume29 HYPERLINK l bookmark260 o Current Document 對比體積 reduced volume29 HYPERLINK l bookmark262 o Current Document 對比溫度 reduced temperature29 HYPERLINK l bookmark264 o Cur

32、rent Document 對比壓力reduced pressure29 HYPERLINK l bookmark266 o Current Document 對稱數 symmetry number29 HYPERLINK l bookmark268 o Current Document 對行反應 reversible reactions29 HYPERLINK l bookmark270 o Current Document 對應狀態原理 principle of corresponding state29 HYPERLINK l bookmark272 o Current Document

33、 多方過程polytropic process29 HYPERLINK l bookmark274 o Current Document 多分子層吸附理論adsorption theory of multi-molecular layers30 HYPERLINK l bookmark276 o Current Document 二級反應second order reaction30 HYPERLINK l bookmark286 o Current Document 二級相變second order phase change30 HYPERLINK l bookmark288 o Curre

34、nt Document 法拉第常數 faraday constant31 HYPERLINK l bookmark290 o Current Document 法拉第定律 Faraday s law31 HYPERLINK l bookmark292 o Current Document 反電動勢 back E.M.F31 HYPERLINK l bookmark294 o Current Document 反滲透 reverse osmosis.31 HYPERLINK l bookmark296 o Current Document 反應分子數 molecularity31 HYPERLI

35、NK l bookmark298 o Current Document 反應級數reaction orders.31 HYPERLINK l bookmark300 o Current Document 反應進度extent of reaction32 HYPERLINK l bookmark302 o Current Document 反應熱 heat of reaction32 HYPERLINK l bookmark304 o Current Document 反應速率rate of reaction32 HYPERLINK l bookmark306 o Current Documen

36、t 反應速率常數constant of reaction rate32 HYPERLINK l bookmark310 o Current Document 范德華常數van der Waals constant32 HYPERLINK l bookmark312 o Current Document 范德華方程van der Waals equation32 HYPERLINK l bookmark314 o Current Document 范德華力van der Waals force32 HYPERLINK l bookmark316 o Current Document 范德華氣體v

37、an der Waals gases32 HYPERLINK l bookmark318 o Current Document 范特霍夫方程van t Hoff equation32 HYPERLINK l bookmark320 o Current Document 范特霍夫規則van t Hoff rule33 HYPERLINK l bookmark322 o Current Document 范特霍夫滲透壓公式van t Hoff equation of osmotic pressure33 HYPERLINK l bookmark324 o Current Document 非基元反

38、應 non-elementary reactions33 HYPERLINK l bookmark326 o Current Document 非體積功 non-volume work33 HYPERLINK l bookmark328 o Current Document 非依時計量學反應time independent stoichiometric reactions33 HYPERLINK l bookmark330 o Current Document 菲克擴散第一定律Fick s first law of diffusion33 HYPERLINK l bookmark332 o C

39、urrent Document 沸點 boiling point33 HYPERLINK l bookmark334 o Current Document 沸點升高elevation of boiling point33 HYPERLINK l bookmark336 o Current Document 費米一狄拉克統計Fermi-Dirac statistics33 HYPERLINK l bookmark338 o Current Document 分布 distribution33 HYPERLINK l bookmark340 o Current Document 分布數 distr

40、ibution numbers34 HYPERLINK l bookmark342 o Current Document 分解電壓decomposition voltage34 HYPERLINK l bookmark344 o Current Document 分配定律 distribution law34 HYPERLINK l bookmark346 o Current Document 分散系統disperse system34 HYPERLINK l bookmark348 o Current Document 分散相 dispersion phase34 HYPERLINK l b

41、ookmark350 o Current Document 分體積 partial volume34 HYPERLINK l bookmark352 o Current Document 分體積定律 partial volume law34 HYPERLINK l bookmark354 o Current Document 分壓 partial pressure34 HYPERLINK l bookmark356 o Current Document 分壓定律 partial pressure law34 HYPERLINK l bookmark358 o Current Document

42、分子反應力學 mechanics of molecular reactions34 HYPERLINK l bookmark360 o Current Document 分子間力 intermolecular force34 HYPERLINK l bookmark362 o Current Document 分子蒸餾molecular distillation35 HYPERLINK l bookmark364 o Current Document 圭寸閉系統 closed system35 HYPERLINK l bookmark366 o Current Document 附加壓力 ex

43、cess pressure.35 HYPERLINK l bookmark368 o Current Document 弗羅因德利希吸附經驗式 Freundlich empirical formula of adsorption35 HYPERLINK l bookmark370 o Current Document 負極 negative pole35 HYPERLINK l bookmark372 o Current Document 負吸附 negative adsorption35 HYPERLINK l bookmark374 o Current Document 復合反應compo

44、site reaction35 HYPERLINK l bookmark376 o Current Document 蓋呂薩克定律 Gay-Lussac law35 HYPERLINK l bookmark378 o Current Document 蓋斯定律Hess law35 HYPERLINK l bookmark380 o Current Document 甘汞電極calomel electrode35 HYPERLINK l bookmark382 o Current Document 感膠離子序 lyotropic series35 HYPERLINK l bookmark388

45、o Current Document 杠桿規貝 Ulever rule35 HYPERLINK l bookmark390 o Current Document 高分子溶液 macromolecular solution 36 HYPERLINK l bookmark392 o Current Document 高會溶點upper consolute point36 HYPERLINK l bookmark394 o Current Document 隔離法 the isolation method36 HYPERLINK l bookmark396 o Current Document 格羅

46、塞斯一德雷珀定律Grotthus-Draoer s law36隔離系統 isolated system37根均方速率 root-mean-square speed37功 work37功函 work content37共軛溶液conjugate solution37共沸溫度azeotropic temperature37構型熵 configurational entropy37孤立系統isolated system37固溶膠 solid sol37 HYPERLINK l bookmark402 o Current Document 固態混合物 solid solution38 HYPERLIN

47、K l bookmark404 o Current Document 固相線 solid phase line38 HYPERLINK l bookmark406 o Current Document 光反應 photoreaction38 HYPERLINK l bookmark408 o Current Document 光化學第二定律 the second law of actinochemistry38 HYPERLINK l bookmark410 o Current Document 光化學第一定律 the first law of actinochemistry 38 HYPER

48、LINK l bookmark412 o Current Document 光敏反應photosensitized reactions38 HYPERLINK l bookmark414 o Current Document 光譜熵spectrumentropy38 HYPERLINK l bookmark416 o Current Document 廣度性質extensive property38 HYPERLINK l bookmark418 o Current Document 廣延量extensivequantity38 HYPERLINK l bookmark420 o Curren

49、t Document 廣延性質extensive property38 HYPERLINK l bookmark422 o Current Document 規定熵stipulatedentropy38 HYPERLINK l bookmark424 o Current Document 過飽和溶液oversaturated solution38 HYPERLINK l bookmark426 o Current Document 過飽和蒸氣 oversaturated vapor38 HYPERLINK l bookmark428 o Current Document 過程 process3

50、9 HYPERLINK l bookmark430 o Current Document 過渡狀態理論 transition state theory39 HYPERLINK l bookmark432 o Current Document 過冷水 super-cooled water39 HYPERLINK l bookmark434 o Current Document 過冷液體 overcooled liquid39 HYPERLINK l bookmark436 o Current Document 過熱液體 overheated liquid39 HYPERLINK l bookma

51、rk438 o Current Document 亥姆霍茲函數 Helmholtz function39 HYPERLINK l bookmark440 o Current Document 亥姆霍茲函數判據Helmholtz function criterion39 HYPERLINK l bookmark442 o Current Document 亥姆霍茲自由能 Helmholtz free energy39 HYPERLINK l bookmark444 o Current Document 亥氏函數 Helmholtz function39 HYPERLINK l bookmark4

52、46 o Current Document 焓 enthalpy39 HYPERLINK l bookmark448 o Current Document 亨利常數 Henry constant39 HYPERLINK l bookmark450 o Current Document 亨利定律 Henry law39 HYPERLINK l bookmark452 o Current Document 恒沸混合物 constant boiling mixture 40 HYPERLINK l bookmark454 o Current Document 恒容摩爾熱容 molar heat ca

53、pacity at constant volume40 HYPERLINK l bookmark456 o Current Document 恒容熱 heat at constant volume40 HYPERLINK l bookmark458 o Current Document 恒夕卜壓constant external pressure40 HYPERLINK l bookmark460 o Current Document 恒壓摩爾熱容molar heat capacity at constant pressure40 HYPERLINK l bookmark462 o Curre

54、nt Document 恒壓熱 heat at constant pressure40 HYPERLINK l bookmark464 o Current Document 化學動力學chemical kinetics40 HYPERLINK l bookmark466 o Current Document 化學反應計量式stoichiometric equation of chemical reaction 40 HYPERLINK l bookmark468 o Current Document 化學反應計量系數stoichiometric coefficient of chemical

55、reaction 40 HYPERLINK l bookmark470 o Current Document 化學反應進度 extent of chemical reaction41 HYPERLINK l bookmark472 o Current Document 化學親合勢chemical affinity41 HYPERLINK l bookmark474 o Current Document 化學熱力學 chemical thermodynamics41 HYPERLINK l bookmark476 o Current Document 化學勢 chemical potential

56、41 HYPERLINK l bookmark482 o Current Document 化學勢判據 chemical potential criterion 41 HYPERLINK l bookmark484 o Current Document 化學吸附 chemisorptions41 HYPERLINK l bookmark486 o Current Document 環境environment41 HYPERLINK l bookmark488 o Current Document 環境熵變 entropy change in environment41 HYPERLINK l

57、bookmark490 o Current Document 揮發度volatility 41 HYPERLINK l bookmark492 o Current Document 混合熵entropy of mixing 42 HYPERLINK l bookmark494 o Current Document 混合物mixture42 HYPERLINK l bookmark496 o Current Document 活度 activity42活化控制 activation control42 HYPERLINK l bookmark498 o Current Document 活化絡合

58、物理論 activated complex theory42 HYPERLINK l bookmark506 o Current Document 活化能 activation energy43 HYPERLINK l bookmark510 o Current Document 霍根-華森圖 Hougen-Watson Chart43 HYPERLINK l bookmark512 o Current Document 基態能級energy level at ground state43 HYPERLINK l bookmark514 o Current Document 基希霍夫公式Kir

59、chhoff formula43 HYPERLINK l bookmark516 o Current Document 基元反應elementary reactions43 HYPERLINK l bookmark518 o Current Document 積分溶解熱integration heat of dissolution 43 HYPERLINK l bookmark520 o Current Document 吉布斯一杜亥姆方程Gibbs-Duhem equation43 HYPERLINK l bookmark522 o Current Document 吉布斯一亥姆霍茲方程Gi

60、bbs-Helmhotz equation43 HYPERLINK l bookmark524 o Current Document 吉布斯函數 Gibbs function43 HYPERLINK l bookmark526 o Current Document 吉布斯函數判據Gibbs function criterion44 HYPERLINK l bookmark528 o Current Document 吉布斯吸附公式 Gibbs adsorption formula44 HYPERLINK l bookmark530 o Current Document 吉布斯 自由能 Gibb