ICS71.080.90

CCSG17

中華人民共和國國家標準

GB/T45372—2025

煤基液相酚類化合物的測定

全二維氣相色譜?質譜/氫火焰離子化

檢測器聯用

Determinationofphenolsinliquidproductsfromcoalchemicalindustry—

Comprehensivetwodimensionalgaschromatography?massspectrometry/

hydrogenflameionizationdetector

2025?02?28發布2025?09?01實施

國家市場監督管理總局

國家標準化管理委員會發布

GB/T45372—2025

目次

前言··························································································································Ⅲ

1范圍·······················································································································1

2規范性引用文件········································································································1

3術語和定義··············································································································1

4原理·······················································································································1

5試劑與材料··············································································································1

6儀器與設備··············································································································2

7取樣·······················································································································3

8試驗步驟·················································································································3

9結果表述·················································································································4

10精密度··················································································································5

11試驗報告···············································································································6

附錄A（資料性）標準溶液的全二維質譜總離子流色譜圖/氫火焰離子化檢測器色譜圖和保留時間····8

附錄B（資料性）不同組分相對于2，6?二氯苯酚的相對校正因子············································11

附錄C（資料性）實驗室間比對試驗得到的統計結果···························································12

Ⅰ

GB/T45372—2025

前言

本文件按照GB/T1.1—2020《標準化工作導則第1部分：標準化文件的結構和起草規則》的規

定起草。

請注意本文件的某些內容可能涉及專利。本文件的發布機構不承擔識別專利的責任。

本文件由全國煤化工標準化技術委員會（SAC/TC469）提出并歸口。

本文件起草單位：太原理工大學、山西省檢驗檢測中心、中國神華煤制油化工有限公司、國家能源

集團寧夏煤業有限責任公司、天津先德科技有限責任公司、中科合成油技術股份有限公司、國能基石化

工科技（上海）有限公司、雪景電子科技（上海）有限公司、北京低碳清潔能源研究院、中北大學、寧夏計

量質量檢驗檢測研究院、昌吉學院、上海兗礦能源科技研發有限公司、懷柔實驗室山西研究院（懷柔實

驗室山西基地）、華北科技學院、內蒙古伊泰煤炭股份有限公司。

本文件主要起草人：劉建偉、黃偉、姜興劍、智紅梅、張乾、李雁如、姜忠軍、陳軍、李藝、李盛勝、白雪梅、

李群花、張旭瑞、孫永躍、李曉峰、于紫薇、蓋青青、張琴清、李淑娟、郭福強、徐震、孫燕、李旺、張曼、

高丹、趙佳穎、袁浩天。

Ⅲ

GB/T45372—2025

煤基液相酚類化合物的測定

全二維氣相色譜?質譜/氫火焰離子化

檢測器聯用

1范圍

本文件描述了全二維氣相色譜?質譜/氫火焰離子化檢測器測定煤基液相酚類化合物的試驗方法。

≤360℃C?C?C?

本文件適用于下列沸點的煤焦油和煤焦化廢水中苯酚、1苯酚、2苯酚、3苯酚、苯二

C?

酚、茚醇、萘酚、1萘酚類化合物的測定：

0.015%C?C?0.035%C?

——煤焦油中苯酚的檢出限為，1苯酚、2苯酚的檢出限為，3苯酚檢出限為

0.15%C?0.35%;

，苯二酚、茚醇、萘酚、1萘酚的檢出限為，且均為質量分數

1.5mg/LC?C?2.5mg/LC?

——煤焦化廢水中苯酚的檢出限為，1苯酚、2苯酚的檢出限為，3苯酚檢

5.0mg/LC?15.0mg/L

出限為，苯二酚、茚醇、萘酚、1萘酚的檢出限為。

2規范性引用文件

下列文件中的內容通過文中的規范性引用而構成本文件必不可少的條款。其中，注日期的引用文

件，僅該日期對應的版本適用于本文件；不注日期的引用文件，其最新版本（包括所有的修改單）適用于

本文件。

GB/T1999焦化油類產品取樣方法

GB/T6682分析實驗室用水規格和試驗方法

HJ494水質采樣技術指導

3術語和定義

本文件沒有需要界定的術語和定義。

4原理

將試樣導入配有一維非極性色譜柱和二維中等極性色譜柱的全二維氣相色譜儀，利用分離器使經

色譜柱分離的組分同步進入質譜檢測器和氫火焰離子化檢測器。根據質譜檢測器產生信號的主要離

子峰、特征離子峰及一維保留時間、二維保留時間共同定性；