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3、ter clusterM. F. Chaplin, Nature Reviews Molecular Cell Biology OHSub-structures of water clusteSub-structures of water clusterYan Zubavicus, science, 2004, 304, 974Lone pair electronsHH五角十二面體水四面體電荷分布五元環鍵角為108 水鍵角為104. 5匹配 512 穩定Sub-structures of water clusteProtonated water clustersMak T C W,Zhou G

4、D. Crystallography in Modern Chemistry : A Resource Book of Crystal Structures ,New York :Wiley ,1992HNO33H2O (H7O3) NO3 (H3O) NO32H2OHSbCl63H2O (H7O3) SbCl6 (H5O2) SbCl6H2OHCl3H2O (H7O3) Cl (H5O2) ClH2O酸的水合物經驗化學式結構式Protonated water clustersMak Protonated water clustersOuter hydration shellInner hyd

5、ration shellBulk water+(ordered)J.-W. Shin, science, 2004, 304, 1137Protonated water clustersOuteProtonated water clustersD. M. Neumark, J. Chem. Phys. 2006, 125, 171102O;H；H-bondsProtonated water clustersD. M.CH4 - water clusters8CH4 46H2O 512 周公度,大學化學,2002,17,54 51262 K.D. Jordan, Science, 2005, 3

6、08, 1765藍色紫色 51262 ，黃色 512 CH4 - water clusters藍色紫色 5126Buck U ,Huisken F. Chem Rev . 2000 ,100 :38632 512 (1/2,1/2,1/2),(0,0,0) 6 51262 (1/4,/1/2,0),(3/4,1/2,0)晶胞化學式 晶系 晶胞參數/pm CH4所處多面體8CH446H2O 立方 1180 2 512 ,6 51262 8CH446H2O在273k， 30大氣壓下形成冰狀晶體-可燃冰1m3可燃冰理論含182m3，實際164m3CH4CH4 - water clustersBuck

7、 U ,Huisken F. Chem Rev .CH4 - water clusters機遇：可用千年 清潔能源挑戰：開采困難 溫室災難第28屆國際地質大會，2006CH4 - water clusters機遇：可用千年第28H. Sato，Chem. Phys. Lett. 2006, 323 ,412CO2-water cluster O(H2O), H, C, O (CO2)CO2,CO在水中溶解度H. Sato，Chem. Phys. Lett. 2006Water clusters in biochemistryWilliam Royer, Ph. Dbiochemistry and molecular pharmacology血紅蛋白CO-血紅蛋白蛋白質子結構水分子簇Water clusters in biochemistryWater clusters in biochemistryH2O， O2， COF97T72T72F97T72T72F97F97CO-血紅蛋白血紅蛋白William Royer, Ph. Dbiochemistry and molecular pharmacologyWater clusters in biochemistryProspect水分子團簇研究從一全